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- W2492137703 abstract "Microstress in reaction‐bonded silicon carbide ( RBS iC) has been measured using piezo‐Raman spectroscopy. Compressive microstresses as high as 2 GPa exist in the silicon phase and tensile microstresses as high as 2.3 GPa exist in the SiC phase of RBSiC. This is much larger than expected for thermoelastic microstress from coefficient of thermal expansion mismatch would provide. Instead the microstresses arise from the crystallization of liquid silicon. During the reaction bonding process, not all of the silicon reacts to form SiC and there is liquid free silicon. The phase transformation of the free silicon from liquid to solid has a large volume expansion, which results in large residual microstress within the silicon and SiC phases of RBS iC." @default.
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- W2492137703 date "2016-07-28" @default.
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- W2492137703 title "Microstress in Reaction-Bonded SiC from Crystallization Expansion of Silicon" @default.
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- W2492137703 doi "https://doi.org/10.1111/jace.14398" @default.
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