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- W2492163802 abstract "In this paper, new methodology is described for characterizing the structures of fluoropolymers. The methods are based on 19F/1HH/13C multiple resonance and 2D NMR experiments, taking advantage of the unique ranges of 19F-19F and 19F-13C couplings. 19F-13C heteronuclear single quantum correlation (HSQC) 2D-NMR experiments based on 1JCF and 2JCF experiments provide short range correlations within monomer units and in many cases help to distinguish between structure fragments identified using 3JFF, 4JFF and 5JFF correlations. COSY and especially selective COSY experiments provide high resolution 2D-NMR experiments with correlations based on 3JFF, 4JFF and 5JFF couplings. These permit identification of long-range structure correlations between monomer units. Examples using poly(hexafluoropropylene oxide) and poly(vinylidene fluoride) are shown." @default.
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- W2492163802 date "2011-01-01" @default.
- W2492163802 modified "2023-09-25" @default.
- W2492163802 title "Advanced Solution 2D-NMR of Fluoropolymers" @default.
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- W2492163802 doi "https://doi.org/10.1021/bk-2011-1077.ch021" @default.
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