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- W2492941487 abstract "Minerals with ion exchange capacity strongly influence the chemical and physical properties of soils and sediments, and the composition of natural waters. The stability and exchange characteristics of these minerals have important practical and theoretical implications to agriculture, pollution control, and petroleum production. Understanding the stability and exchange characteristics of these minerals is presently limited because of uncertainty as to whether equilibria involving mineral structural ions are 1) separate from, or 2) linked to, equilibria involving exchangeable ions. Practical and theoretical applications of mineral and exchange equilibria have proceeded upon one or the other of these opposite assumptions, guaranteeing a large body of questionable data. Calorimetric methods cannot distinguish between separate or linked equilibria in the same sample. For the mineral montmorillonite (an aluminum silicate containing Mg, Fe and other elements), under the restricted conditions where all common ions are measurable, solubility methods also cannot determine whether the two equilibria are separate or linked. However, when gibbsite, Al(OH)3, and hematite, Fe2O3, are allowed to control Al3+ and Fe3+in equilibrium with montmorillonite (at low levels that cannot be measured but which can be accurately calculated), it should be possible to experimentally determine whether or not the two equilibria are linked, using solubility methods." @default.
- W2492941487 created "2016-08-23" @default.
- W2492941487 creator A5002934011 @default.
- W2492941487 date "1979-03-19" @default.
- W2492941487 modified "2023-09-24" @default.
- W2492941487 title "Ion Exchange and Mineral Stability: Are the Reactions Linked or Separate?" @default.
- W2492941487 doi "https://doi.org/10.1021/bk-1979-0093.ch020" @default.
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