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- W2493411203 abstract "The dependence of the swelling ratio on latex particle size and interfacial tension was studied on two polymer latex systems : polystyrene swollen with styrene in the presence of anionic, nonionic, and polymeric surfactants; and polymethyl methacrylate swollen with methyl methacrylate in the presence of anionic surfactants. The equilibrium swelling ratio was obtained by extracting monomer from swollen latex particles with iso-octane, and then determining the monomer concentration in the extract with a UV detector. The particle-water interfacial tension at equilibrium swelling was estimated by the drop volume method. Comparison of the experimental data with Morton's theory defined a monomer-polymer interaction parameter of 0.35 and a corresponding semi-empirical equation describing the swelling of polystyrene latexes with styrene . A monomer-polymer interaction parameter of 0.45 and a semi-empirical equation was obtained for the swelling of polymethyl methacrylate latexes with methyl methacrylate. A generalized model which takes into account the effect of water dissolved in the swollen particles as well as in the monomer phase is presented. Comparison of the swelling data with the theoretical curves from this model is shown." @default.
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- W2493411203 date "1982-09-24" @default.
- W2493411203 modified "2023-09-24" @default.
- W2493411203 title "Modeling the Equilibrium Swelling of Latex Particles with Monomers" @default.
- W2493411203 doi "https://doi.org/10.1021/bk-1982-0197.ch011" @default.
- W2493411203 hasPublicationYear "1982" @default.
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