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- W2493553275 endingPage "11646" @default.
- W2493553275 startingPage "11642" @default.
- W2493553275 abstract "Reported herein is an enantiodivergent synthesis of chiral biaryls by a chiral phosphoric acid catalyzed asymmetric transfer hydrogenation reaction. Upon treatment of biaryl lactols with aromatic amines and a Hantzsch ester in the presence of chiral phosphoric acid, dynamic kinetic resolution (DKR) involving a reductive amination reaction proceeded smoothly to furnish both R and S isomers of chiral biaryls with excellent enantioselectivities by proper choice of hydroxyaniline derivative. This trend was observed in wide variety of substrates, and various chiral biphenyl and phenyl naphthyl adducts were synthesized with satisfactory enantioselectivities in enantiodivergent fashion. The enantiodivergent synthesis of synthetically challenging, chiral o-tetrasubstituted biaryls were also accomplished, and suggests high synthetic potential of the present method." @default.
- W2493553275 created "2016-08-23" @default.
- W2493553275 creator A5001749902 @default.
- W2493553275 creator A5047852267 @default.
- W2493553275 creator A5072245581 @default.
- W2493553275 date "2016-08-05" @default.
- W2493553275 modified "2023-09-30" @default.
- W2493553275 title "Enantiodivergent Atroposelective Synthesis of Chiral Biaryls by Asymmetric Transfer Hydrogenation: Chiral Phosphoric Acid Catalyzed Dynamic Kinetic Resolution" @default.
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