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- W2495019078 abstract "H2S and CO2 are observed in natural gas in the Western Canada Sedimentary Basin (WCSB) and concentrations increase with depth and temperature. Paleozoic waters are saline (70-250 g/L TDS) and approach equilibrium with anhydrite, the probable sulfur source for H2S. The 13C composition of hydrocarbon gases associated with H2S is consistent with hydrocarbon oxidation. Molar volumes of anhydrite and H2S are similar at reservoir temperatures and pressures. Calculations show that 0.35 X H2S could be formed by 1 volume % anhydrite. These observations are consistent with a closed-system origin for H2S. Modeling of thermochemical sulfate reduction (TSR) shows that 75% of the porosity created by dissolution of anhydrite in a closed system is lost to calcite precipitation. Moving H2S away from the site at which TSR takes place creates more porosity, however the isotopic data do not support an open system model." @default.
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- W2495019078 date "1995-05-05" @default.
- W2495019078 modified "2023-09-27" @default.
- W2495019078 title "Controls on the Origin and Distribution of Elemental Sulfur, H<sub>2</sub>S, and CO<sub>2</sub> in Paleozoic Hydrocarbon Reservoirs in Western Canada" @default.
- W2495019078 doi "https://doi.org/10.1021/bk-1995-0612.ch024" @default.
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