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- W2495056593 abstract "This chapter provides a background research in the area of thermodynamics and kinetics of phase transitions in simple, small molecules. It reviews, thermodynamic point of view, phase transitions in single-component systems, including liquid–gas, crystalline solid–liquid, crystalline solid–solid, and transitions involving mesophases. The kinetic aspects of crystallization, melting, and mesophase transitions is discussed specifically. The thermodynamic descriptions are then extended to multiple component systems, with particular attention to liquid–liquid phase separation, crystalline solid–liquid, and mesophase–liquid transitions of binary mixtures. A description of the kinetics of liquid–liquid phase separation in binary mixtures in the initial, intermediate, and late coarsening stages is also provided. Three macroscopic thermodynamic properties—volume, pressure, and temperature—determine the physical state of a phase. Whether a phase transition is possible or impossible is determined by thermodynamics, but how the transition progresses to the final state is determined by the kinetics of the phase transformation. Kinetics, therefore, is important in discussing phase transitions. Kinetics usually assumes a microscopic model of how the particles activate during the transition, then uses this model to understand macroscopic phase transition rates, which are usually measured by diffraction, calorimetric, spectroscopic, or microscopic experimental techniques." @default.
- W2495056593 created "2016-08-23" @default.
- W2495056593 creator A5080730961 @default.
- W2495056593 date "2008-01-01" @default.
- W2495056593 modified "2023-09-25" @default.
- W2495056593 title "Thermodynamics and Kinetics of Phase Transitions" @default.
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- W2495056593 doi "https://doi.org/10.1016/b978-0-444-51911-5.00002-5" @default.
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