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- W2495360830 abstract "Hifmmodecdotelsetextperiodcenteredfi{}N${mathrm{H}}_{4}$${(mathrm{C}mathrm{l}mathrm{C}{mathrm{H}}_{2}mathrm{C}mathrm{O}mathrm{O})}_{2}$ is ferroelectric below -145ifmmode^circelsetextdegreefi{}C. At room temperature, the crystal is monoclinic with $a=10.56$, $b=11.51$, $c=8.36$ AA{}, $ensuremath{beta}=119ifmmode^circelsetextdegreefi{}{50}^{ensuremath{'}}$, and space group is most probably $frac{C2}{c}$. The density is 1.528 g/${mathrm{cm}}^{3}$. The unit cell contains four formula units. The ferroelectric axis is along the [102] direction. The spontaneous polarization is 0.18ensuremath{mu}C/${mathrm{cm}}^{2}$ and the coercive field is 1.2 kV/cm at -195ifmmode^circelsetextdegreefi{}C. Along the ferroelectric axis the dielectric constants obey the Curie-Weiss law with a Curie-Weiss constant of 44ifmmode^circelsetextdegreefi{}C. The domain-wall motion seems to contribute to the initial dielectric constants if the frequency of applied ac field is as low as 10 kc/sec. The phase transition seems to be of the first order." @default.
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- W2495360830 date "1966-12-09" @default.
- W2495360830 modified "2023-09-25" @default.
- W2495360830 title "Ferroelectricity in H·NH4(ClCH2COO)2" @default.
- W2495360830 cites W1993766471 @default.
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- W2495360830 doi "https://doi.org/10.1103/physrev.152.495" @default.
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