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- W2495367025 abstract "Results of dynamic mechanical spectroscopy and Fourier-transform infrared spectroscopy are presented for a glassy polymer (ethylene vinyl alcohol copolymer, EVOH) exposed to a plasticizing solvent (methanol), a non-plasticizing fluid (toluene), and mixtures of the two. Quantitative FTIR measurements on thin films of EVOH are used to analyze the sorption and diffusion characteristics of the systems. The presence of even minute quantities of methanol in toluene allows toluene to penetrate EVOH to a significant extent. We interpret the observed large increase in toluene uptake in the presence of small amounts of methanol as due to the fact that the methanol present in the solvent mixture is preferentially absorbed by the EVOH and plasticizes it, thereby lowering its glass transition temperature and eliminating the kinetic constraints preventing penetration by toluene." @default.
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- W2495367025 date "1995-05-05" @default.
- W2495367025 modified "2023-10-17" @default.
- W2495367025 title "Solvent-Induced Changes in the Glass Transition Temperature of Ethylene—Vinyl Alcohol Copolymer Studied Using Fourier Transform IR and Dynamic Mechanical Spectroscopy" @default.
- W2495367025 doi "https://doi.org/10.1021/bk-1995-0598.ch031" @default.
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