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- W2495388645 abstract "In 1978 Makosza and Golinski uncovered a new aromatic nucleophilic substitution reaction: vicarious nucleophilic substitution of hydrogen (VNS). In the intervening more than three decades, this powerful new reaction has seen many synthetic applications, as reviewed several times by Makosza. Notably, the synthesis of indoles via VNS has received the most attention by Makosza and others. In some Makosza indolizations, a VNS reaction is employed to prepare the immediate indole precursor. The cyanoalkylation-hydrogenation sequence is also applied to the preparation of 4-, 5-, 6-, and 7-hydroxy and -methoxyindoles. A collection of Makosza's and other authors' indolizations that involve a VNS synthesis of the indole precursor are also presented in the chapter." @default.
- W2495388645 created "2016-08-23" @default.
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- W2495388645 date "2016-06-17" @default.
- W2495388645 modified "2023-09-23" @default.
- W2495388645 title "Mąkosza Indole Synthesis" @default.
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- W2495388645 doi "https://doi.org/10.1002/9781118695692.ch43" @default.
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