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- W2495453913 abstract "I am not going to discuss early transition metal oxide or alkoxide chemistry here. Instead I would like to use the few minutes allotted me to describe our work with low valent dimers of tantalum and tungsten. Professor McCarley will no doubt see his influence on our work and forgive this digression from the topic of his excellent presentation. The synthesis of the first quadruply bonded tungsten(II) carboxylate, W2(O2CCF3)4 (hereafter referred to as W2(TFA)4. was reported by us last year (1). The structure of its diglyme adduct, W2(TFA)4·2/3 diglyme is shown in Figure 1. This particular view shows the partial contents of two unit cells and it emphasizes the tridentate nature of the axially coordinated polyether which stiches W2(TFA)4 units together in the solid state. We now have in hand several other adducts of W2(TFA)4 and one of these, W2(TFA)4·2PPh3 (an axial adduct), has been structurally characterized (2). Despite many" @default.
- W2495453913 created "2016-08-23" @default.
- W2495453913 creator A5022013208 @default.
- W2495453913 date "1983-03-03" @default.
- W2495453913 modified "2023-09-24" @default.
- W2495453913 title "Low-Valent Dimers of Tantalum and Tungsten" @default.
- W2495453913 doi "https://doi.org/10.1021/bk-1983-0211.ch019" @default.
- W2495453913 hasPublicationYear "1983" @default.
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