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- W2495511933 abstract "Typical transport properties of linear polymers in solution may include sedimentation, diffusion, and viscosity. For polyelectrolytes, in addition, electrophoresis may be the most important. This chapter discusses the essential differences between transport phenomena of nonionic polymers and polyelectrolytes. In sedimentation and diffusion, counter-ions that constitute the ionic atmosphere migrate along with central polyions in the same direction. In transport phenomena such as sedimentation, diffusion, and viscosity, random-flight coils of flexible linear polymers are often represented by a porous sphere with radius R in which N elements of a chain are uniformly distributed. The polymer concentration dependence of the sedimentation velocity of polyelectrolytes is not only due to the hydrodynamic interaction between polymer molecules but also due to the electrostatic interaction between polyion molecules and counter-ions. Some polyelectrolytes have a distribution in charge density of molecules. This includes carboxymethyl cellulose (CMC), which is prepared by substituting cellulose with monochloroacetic acid." @default.
- W2495511933 created "2016-08-23" @default.
- W2495511933 creator A5023276521 @default.
- W2495511933 date "2015-09-15" @default.
- W2495511933 modified "2023-09-23" @default.
- W2495511933 title "Transport Phenomena of Linear Polyelectrolytes" @default.
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- W2495511933 doi "https://doi.org/10.1002/9781119057338.ch6" @default.
- W2495511933 hasPublicationYear "2015" @default.
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