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• W2495514684 abstract "The new osmates(VI), Sr2OsO5 and Sr7Os4O19, feature quasi-1-D polyoxo anions, consisting of corner sharing [OsO6] octahedra. In both compounds, the magnetic moment at T = 300 K is significantly lower (1.2-1.3 μB/Os-atom) than the value expected for S = 1. For neither of the new osmates(VI) is any evidence for long-range magnetic order found. For Sr7Os4O19, magnetic susceptibility suggests an antiferromagnetic ordering at TN = 43(3) K; however, no corresponding anomaly is visible in specific heat. Both compounds are semiconductors." @default.
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• W2495514684 date "2016-08-01" @default.
• W2495514684 modified "2023-09-27" @default.
• W2495514684 title "Sr₂OsO₅ and Sr₇Os₄O₁₉, Two Structurally Related, Mott Insulating Osmates(VI) Exhibiting Substantially Reduced Spin Paramagnetic Response" @default.
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• W2495514684 doi "https://doi.org/10.1021/acs.inorgchem.6b01354" @default.
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