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- W2495576215 abstract "Two distinct structural elements that render π-systems nonplanar, i.e., geodesic curvature and helical motifs, have been combined into new polyarenes that contain both features. The resultant corannulene-[n]helicenes (n = 5, 6) show unique molecular dynamics in their enantiomerization processes, including inversion motions of both the bowl and the helix. Optical resolution of a corannulene-based skeletally chiral molecule was also achieved for the first time, and the influence of the bowl-motif annulation on the chiroptical properties was investigated." @default.
- W2495576215 created "2016-08-23" @default.
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- W2495576215 date "2016-08-04" @default.
- W2495576215 modified "2023-09-29" @default.
- W2495576215 title "Corannulene–Helicene Hybrids: Chiral π-Systems Comprising Both Bowl and Helical Motifs" @default.
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- W2495576215 doi "https://doi.org/10.1021/acs.orglett.6b01801" @default.
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