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- W2495606201 abstract "Publisher Summary The dynamics of making and breaking bonds at surfaces is concerned with understanding the elementary steps occurring at surfaces in terms of the individual atomic and molecular forces, and the motions that these induce during the process of chemical change. Usually this chemistry is only measured as a kinetic process at thermal equilibrium so that details of the dynamics are unobservable. However, when one of the reactants or products is in the gas phase, i.e., in gas-surface chemistry, experiments/theory probing the detailed dynamics are possible. This chapter focuses on the dynamics of gas-surface chemistry. Both the theoretical and experimental methodology inherent in such an approach, borrow much from the study of the dynamics of atom–molecule chemical reactions in the gas phase. This chapter summarizes the current state of knowledge of the dynamics of bond making and breaking at the gas-surface interface. It begins with an introduction of general concepts necessary to understand the dynamics of chemical change at surfaces, a few of the experimental techniques currently in use Following this, it summarizes a few selected examples of the different types of chemical change at surfaces. Finally, it sheds light on how well ‘first principles’ dynamics can now quantitatively interpret detailed experiments." @default.
- W2495606201 created "2016-08-23" @default.
- W2495606201 creator A5048686195 @default.
- W2495606201 date "2008-01-01" @default.
- W2495606201 modified "2023-09-26" @default.
- W2495606201 title "The Dynamics of Making and Breaking Bonds at Surfaces" @default.
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