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- W2495892013 abstract "Novel vinyl liquid crystalline (l.c.) polymers were synthesized with the UV-sensitive p-methoxycinnamate chromophore incorporated into the side chain of the polymers. The objective of this synthesis was to determine if a molecularly organized environment could influence the yield of a chemical reaction in the solid state. The investigation into the photochemical and physical processes of these thin films revealed that the photodimerization of the p-methoxycinnamate moieties was very sensitive to their geometrical arrangement in the polymer matrix. The relative quantum yield of cyclobutane formation increased by a factor of approximately 8 for the l.c. p-methoxycinnamate film compared to its amorphous analog. This quantum yield approaches the theoretical limit for this system." @default.
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- W2495892013 date "1990-08-24" @default.
- W2495892013 modified "2023-09-25" @default.
- W2495892013 title "Synthesis, Characterization, and Photochemistry of a Cinnamate-Containing Liquid-Crystalline Side-Chain Polymer" @default.
- W2495892013 doi "https://doi.org/10.1021/bk-1990-0435.ch011" @default.
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