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• W2496003866 abstract "We investigate the effect of shape on reversible adsorption kinetics using colloidal polystyrene dimers near a solid glass surface as a model system. The interaction between colloid and wall is tuned using electrostatic, depletion, and gravity forces to produce a double-well potential. The dwell time in each of the potential wells is measured from long duration particle trajectories. The height of each monomer relative to the glass surface is measured to a resolution of <20 nm by in-line holographic microscopy. The measured transition probability distributions are used in kinetic equations to describe the flux of particles to and from the surface. The dimers are compared to independent isolated monomers to determine the effects of shape on adsorption equilibria and kinetics. To elucidate these differences, we consider both mass and surface coverage and two definitions of surface coverage. The results show that dimers with single coverage produce slower adsorption, lower surface coverage, and higher mass coverage in comparison to those of monomers, while dimers with double coverage adsorb faster and result in higher surface coverage." @default.
• W2496003866 created "2016-08-23" @default.
• W2496003866 creator A5042449763 @default.
• W2496003866 creator A5087905971 @default.
• W2496003866 date "2016-08-17" @default.
• W2496003866 modified "2023-09-28" @default.
• W2496003866 title "Reversible Adsorption Kinetics of Near Surface Dimer Colloids" @default.
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• W2496003866 doi "https://doi.org/10.1021/acs.langmuir.6b02019" @default.
• W2496003866 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/5064446" @default.
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