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- W2496018222 abstract "Magnetically recoverable copper oxide catalysts prepared by sol-immobilization method exhibited interesting properties for the allylic oxidation of cyclohexene with molecular oxygen as the sole oxidant. The catalysts were prepared by immobilization of pre-synthesized PVA (polyvinyl alcohol)-stabilized Cu2O nanoparticles (NPs) on a magnetically recoverable support; the catalyst was further oxidized to CuO NPs after calcination at 600 °C. Both catalysts can selectively oxidize cyclohexene through allylic oxidation to give 2-cyclohexene-1-one as the main product, but CuO was identified as the most active species providing 90% cyclohexene conversion and 96% selectivity for allylic products under 100 °C and 4 bar pressure of O2 for 6 h of reaction time. The catalysts were magnetically recovered without metal leaching and could be reused in at least six consecutive runs." @default.
- W2496018222 created "2016-08-23" @default.
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- W2496018222 date "2017-01-01" @default.
- W2496018222 modified "2023-10-10" @default.
- W2496018222 title "Magnetically recoverable copper oxide catalysts for aerobic allylic oxidation of cyclohexene" @default.
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- W2496018222 doi "https://doi.org/10.1016/j.molcata.2016.07.044" @default.
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