Matches in SemOpenAlex for { <https://semopenalex.org/work/W2496033634> ?p ?o ?g. }
Showing items 1 to 69 of
69
with 100 items per page.
- W2496033634 endingPage "168" @default.
- W2496033634 startingPage "157" @default.
- W2496033634 abstract "Alcohols and Grignard reagents react with the hydrogen-terminated surfaces of porous silicon, Si(100), and Si(111) and form covalently attached organic layers. With alcohols, the reaction occurs at temperatures of 40 to 90 °C and is compatible with the presence of functionalities such as halides, olefins, esters, and carboxylic acids within the reacting alcohol; the resulting films attach to the silicon surface by Si-O linkages. With Grignard reagents, the reaction occurs at room temperature and forms Si-C bonds with the support. For both the alcohols and Grignard reagents, their attachment to the surface occurs concurrently with the cleavage of Si-Si bonds and an etching of the silicon framework during the reaction. With Grignard reagents, the level of etching is slight and easily contolled, thereby allowing straightforward, reproducible formation of stable films on the porous and crystalline silicon supports. For both reactions, the organic layer is directly attached to the silicon substrate." @default.
- W2496033634 created "2016-08-23" @default.
- W2496033634 creator A5021165844 @default.
- W2496033634 creator A5070940401 @default.
- W2496033634 date "1999-07-08" @default.
- W2496033634 modified "2023-10-13" @default.
- W2496033634 title "Covalent Modification of Hydrogen-Terminated Silicon Surfaces" @default.
- W2496033634 doi "https://doi.org/10.1021/bk-1999-0727.ch012" @default.
- W2496033634 hasPublicationYear "1999" @default.
- W2496033634 type Work @default.
- W2496033634 sameAs 2496033634 @default.
- W2496033634 citedByCount "2" @default.
- W2496033634 countsByYear W24960336342012 @default.
- W2496033634 crossrefType "book-chapter" @default.
- W2496033634 hasAuthorship W2496033634A5021165844 @default.
- W2496033634 hasAuthorship W2496033634A5070940401 @default.
- W2496033634 hasConcept C100460472 @default.
- W2496033634 hasConcept C111368507 @default.
- W2496033634 hasConcept C127313418 @default.
- W2496033634 hasConcept C127413603 @default.
- W2496033634 hasConcept C171560689 @default.
- W2496033634 hasConcept C178790620 @default.
- W2496033634 hasConcept C179104552 @default.
- W2496033634 hasConcept C180577832 @default.
- W2496033634 hasConcept C185592680 @default.
- W2496033634 hasConcept C188027245 @default.
- W2496033634 hasConcept C192562407 @default.
- W2496033634 hasConcept C2776685891 @default.
- W2496033634 hasConcept C2777289219 @default.
- W2496033634 hasConcept C2779227376 @default.
- W2496033634 hasConcept C40875361 @default.
- W2496033634 hasConcept C42360764 @default.
- W2496033634 hasConcept C544956773 @default.
- W2496033634 hasConceptScore W2496033634C100460472 @default.
- W2496033634 hasConceptScore W2496033634C111368507 @default.
- W2496033634 hasConceptScore W2496033634C127313418 @default.
- W2496033634 hasConceptScore W2496033634C127413603 @default.
- W2496033634 hasConceptScore W2496033634C171560689 @default.
- W2496033634 hasConceptScore W2496033634C178790620 @default.
- W2496033634 hasConceptScore W2496033634C179104552 @default.
- W2496033634 hasConceptScore W2496033634C180577832 @default.
- W2496033634 hasConceptScore W2496033634C185592680 @default.
- W2496033634 hasConceptScore W2496033634C188027245 @default.
- W2496033634 hasConceptScore W2496033634C192562407 @default.
- W2496033634 hasConceptScore W2496033634C2776685891 @default.
- W2496033634 hasConceptScore W2496033634C2777289219 @default.
- W2496033634 hasConceptScore W2496033634C2779227376 @default.
- W2496033634 hasConceptScore W2496033634C40875361 @default.
- W2496033634 hasConceptScore W2496033634C42360764 @default.
- W2496033634 hasConceptScore W2496033634C544956773 @default.
- W2496033634 hasLocation W24960336341 @default.
- W2496033634 hasOpenAccess W2496033634 @default.
- W2496033634 hasPrimaryLocation W24960336341 @default.
- W2496033634 hasRelatedWork W2020927774 @default.
- W2496033634 hasRelatedWork W2076531063 @default.
- W2496033634 hasRelatedWork W2104174733 @default.
- W2496033634 hasRelatedWork W2308354601 @default.
- W2496033634 hasRelatedWork W2349066402 @default.
- W2496033634 hasRelatedWork W2387077136 @default.
- W2496033634 hasRelatedWork W2949841654 @default.
- W2496033634 hasRelatedWork W2951695663 @default.
- W2496033634 hasRelatedWork W4234879979 @default.
- W2496033634 hasRelatedWork W4294031353 @default.
- W2496033634 isParatext "false" @default.
- W2496033634 isRetracted "false" @default.
- W2496033634 magId "2496033634" @default.
- W2496033634 workType "book-chapter" @default.