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- W2496207810 abstract "Polarographic techniques are capable of measuring a variety of sulfur species. These species include thiosulfate, sulfite, polythionates, sulfide, organic sulphydryl groups and inorganic and organic polysulfides. All of these can be produced in salt marsh porewaters as a result of sulfate reduction and the consequent oxidation of sulfide and sulfide minerals. Other wet and instrumental methods generally are not capable of measuring all of these sulfur species or distinguishing between these species. Sulfur speciation in the porewaters of two salt marshes (Great Marsh, Delaware and Great Sippewissett, Cape Cod, Massachusetts) are presented. A major finding is that the porewaters from Great Sippewissett salt marsh are dominated by inorganic sulfur species throughout the depth profile. However, Great Marsh, Delaware porewaters are dominated by organic sulphydryl species at millimolar concentrations from the surface to 12 cm and by inorganic sulfur species below 12 cm. Glutathione may be the thiol principally responsible for the field observations. The physical and geochemical characteristics of the two salt marshes differ widely and appear to be related to the differences in sulfur chemistry. There appears to be an interconversion between the inorganic and organic forms of sulfur in Great Marsh. Pyrite oxidation may be important to the formation of thiols." @default.
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- W2496207810 date "1986-04-21" @default.
- W2496207810 modified "2023-10-18" @default.
- W2496207810 title "Speciation of Dissolved Sulfur in Salt Marshes by Polarographic Methods" @default.
- W2496207810 doi "https://doi.org/10.1021/bk-1986-0305.ch020" @default.
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