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- W2497133677 abstract "Heat capacity is the key thermodynamic property of a material. It is well enough understood to permit, when determined over a wide range of temperature, the connection between macroscopic thermodynamic properties and microscopic structure and motion. Through the knowledge of heat capacity the other thermodynamic functions, namely enthalpy, entropy, and Gibbs energy can be derived. In these equations T1, T2 . . . represent equilibrium first order transition temperatures and ΔH1, ΔH2 . . . the corresponding equilibrium transition enthalpies. H0 is the enthalpy of the material analyzed at 0 K. Heat capacity theory permits a correlation with the chemical structure of the repeating unit (1-3). In the solid state, only vibrational contributions need to be considered (skeletal and group vibrations). For an approximate discussion of the skeletal vibrations, the molecule is considered to be a string of structureless beads of the given formula weight. For linear macromolecules with similar" @default.
- W2497133677 created "2016-08-23" @default.
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- W2497133677 date "1982-09-24" @default.
- W2497133677 modified "2023-09-27" @default.
- W2497133677 title "Advanced Thermal Analysis System (ATHAS) Polymer Heat Capacity Data Bank" @default.
- W2497133677 doi "https://doi.org/10.1021/bk-1982-0197.ch021" @default.
- W2497133677 hasPublicationYear "1982" @default.
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