FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2497492912> ?p ?o ?g. }

• W2497492912 abstract "This chapter discusses that the reactivity of octahedral metal complexes has been the subject of a large number of investigations and the results obtained have been the topic of several recent reviews. In spite of the large volume of data, there are few cases where the detailed aspects of the reaction mechanism have been fully established. Generally, the usual kinetic approach leaves considerable uncertainty as to the structure of the transition state. The use of macrocyclic amine ligands has led to many new developments and has allowed information to be gathered regarding the dependence of lability upon factors such as ring size, unsaturation in the macrocycle, ring substituents and ligand configuration. The present chapter concentrates on complexes of the metal (III) oxidation state (Co (III), Cr (III), Ru (III)) as many of these reactions have been the subject of detailed study. The chapter discusses that stereochemical change can be considered in terms of a dissociative mechanism. There are only small energy differences between the square pyramidal and trigonal bipyramidal stereochemistries produced in a dissociative reaction. A number of factors may favor one over the other." @default.
• W2497492912 created "2016-08-23" @default.
• W2497492912 creator A5059161404 @default.
• W2497492912 date "2000-01-01" @default.
• W2497492912 modified "2023-09-27" @default.
• W2497492912 title "Substitution Reactions of Octahedral Complexes" @default.
• W2497492912 cites W1972221252 @default.
• W2497492912 cites W1982773219 @default.
• W2497492912 cites W1987927417 @default.
• W2497492912 cites W1988487719 @default.
• W2497492912 cites W1988928056 @default.
• W2497492912 cites W1996115272 @default.
• W2497492912 cites W2000742985 @default.
• W2497492912 cites W2005367689 @default.
• W2497492912 cites W2026340865 @default.
• W2497492912 cites W2042261638 @default.
• W2497492912 cites W2050226671 @default.
• W2497492912 cites W2055740766 @default.
• W2497492912 cites W2059896304 @default.
• W2497492912 cites W2060572918 @default.
• W2497492912 cites W2071407931 @default.
• W2497492912 cites W2072155327 @default.
• W2497492912 cites W2081181128 @default.
• W2497492912 cites W2086987600 @default.
• W2497492912 cites W2100358918 @default.
• W2497492912 cites W2123505439 @default.
• W2497492912 cites W2159076956 @default.
• W2497492912 cites W2369004914 @default.
• W2497492912 cites W2605024223 @default.
• W2497492912 cites W3024109867 @default.
• W2497492912 cites W3136451559 @default.
• W2497492912 cites W3139085117 @default.
• W2497492912 cites W2052374371 @default.
• W2497492912 doi "https://doi.org/10.1533/9781782420637.58" @default.
• W2497492912 hasPublicationYear "2000" @default.
• W2497492912 type Work @default.
• W2497492912 sameAs 2497492912 @default.
• W2497492912 citedByCount "0" @default.
• W2497492912 crossrefType "book-chapter" @default.
• W2497492912 hasAuthorship W2497492912A5059161404 @default.
• W2497492912 hasConcept C111592845 @default.
• W2497492912 hasConcept C115624301 @default.
• W2497492912 hasConcept C116569031 @default.
• W2497492912 hasConcept C142724271 @default.
• W2497492912 hasConcept C147597530 @default.
• W2497492912 hasConcept C149997192 @default.
• W2497492912 hasConcept C170493617 @default.
• W2497492912 hasConcept C178790620 @default.
• W2497492912 hasConcept C185592680 @default.
• W2497492912 hasConcept C188027245 @default.
• W2497492912 hasConcept C198819137 @default.
• W2497492912 hasConcept C201268389 @default.
• W2497492912 hasConcept C204787440 @default.
• W2497492912 hasConcept C2776910235 @default.
• W2497492912 hasConcept C2780378348 @default.
• W2497492912 hasConcept C55493867 @default.
• W2497492912 hasConcept C71240020 @default.
• W2497492912 hasConcept C71924100 @default.
• W2497492912 hasConcept C8010536 @default.
• W2497492912 hasConceptScore W2497492912C111592845 @default.
• W2497492912 hasConceptScore W2497492912C115624301 @default.
• W2497492912 hasConceptScore W2497492912C116569031 @default.
• W2497492912 hasConceptScore W2497492912C142724271 @default.
• W2497492912 hasConceptScore W2497492912C147597530 @default.
• W2497492912 hasConceptScore W2497492912C149997192 @default.
• W2497492912 hasConceptScore W2497492912C170493617 @default.
• W2497492912 hasConceptScore W2497492912C178790620 @default.
• W2497492912 hasConceptScore W2497492912C185592680 @default.
• W2497492912 hasConceptScore W2497492912C188027245 @default.
• W2497492912 hasConceptScore W2497492912C198819137 @default.
• W2497492912 hasConceptScore W2497492912C201268389 @default.
• W2497492912 hasConceptScore W2497492912C204787440 @default.
• W2497492912 hasConceptScore W2497492912C2776910235 @default.
• W2497492912 hasConceptScore W2497492912C2780378348 @default.
• W2497492912 hasConceptScore W2497492912C55493867 @default.
• W2497492912 hasConceptScore W2497492912C71240020 @default.
• W2497492912 hasConceptScore W2497492912C71924100 @default.
• W2497492912 hasConceptScore W2497492912C8010536 @default.
• W2497492912 hasLocation W24974929121 @default.
• W2497492912 hasOpenAccess W2497492912 @default.
• W2497492912 hasPrimaryLocation W24974929121 @default.
• W2497492912 hasRelatedWork W110526868 @default.
• W2497492912 hasRelatedWork W1697783370 @default.
• W2497492912 hasRelatedWork W1734267289 @default.
• W2497492912 hasRelatedWork W1797651555 @default.
• W2497492912 hasRelatedWork W193331709 @default.
• W2497492912 hasRelatedWork W1964022675 @default.
• W2497492912 hasRelatedWork W1964860907 @default.
• W2497492912 hasRelatedWork W1998584174 @default.
• W2497492912 hasRelatedWork W2086241447 @default.
• W2497492912 hasRelatedWork W2134995008 @default.
• W2497492912 hasRelatedWork W2141715367 @default.
• W2497492912 hasRelatedWork W2476772383 @default.
• W2497492912 hasRelatedWork W2950548009 @default.
• W2497492912 hasRelatedWork W2950663889 @default.
• W2497492912 hasRelatedWork W2951642972 @default.
• W2497492912 hasRelatedWork W2951781309 @default.
• W2497492912 hasRelatedWork W60235075 @default.
• W2497492912 hasRelatedWork W959951605 @default.
• W2497492912 hasRelatedWork W971983378 @default.

• next