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- W2497560994 abstract "The search for new high band gap materials with novel optical and magnetic properties has lead us to investigate mixed Cd/Mn systems in alkali metal polychalcogenide molten salts. The synthesis of several members of the solid solution K{sub 2}Cd{sub 3-x}Mn{sub x}S{sub 4} has been accomplished in a K{sub 2}S{sub x} flux. The materials crystallize in the novel, 2-D K{sub 2}Cd{sub 3}S{sub 4} structure type when x 2, another structure type is established. It bears a polytypic relationship to the known structure of Cs{sub 2}Zn{sub 3}S{sub 4}. A third structure is stabilized when x=3. The cell volume of the series obeys Vegard`s Law. The electronic absorbtion spectra of the compounds feature absorptions due to both S-->Cd and S-->Mn charge transfer. The light emission, magnetic and thermal properties of the materials will be presented." @default.
- W2497560994 created "2016-08-23" @default.
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- W2497560994 date "1995-12-31" @default.
- W2497560994 modified "2023-09-27" @default.
- W2497560994 title "Synthesis and characterization of K{sub 2}Cd{sub 3-x}Mn{sub x}S{sub 4} solid solutions" @default.
- W2497560994 hasPublicationYear "1995" @default.
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