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- W2497567508 abstract "This chapter provides an overview of virtual bound state contribution to the crystal field potential. The contribution of the so-called virtual bound states or semilocalized states within atomic core area is one of the three main mechanisms specific for the metallic state being responsible for the crystal field potential in metallic phases. The two remaining are the electrostatic contribution of atomic cores screened by the conduction electrons and hybridization effect of the localized and conduction band states. Two features distinguish this mechanism from the others. First is its two-stage, indirect nature leading in consequence to the effect being opposite to that produced by the immediate interaction and the second is a collective character of this effect hindering its decomposition into the intrinsic contributions. The contribution of the 5 d virtual bound state into the crystal field potential of the 4 f open-shell electrons in the lanthanide compounds is a model example of this mechanism, and this chapter analyzes the example in detail." @default.
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- W2497567508 date "2000-01-01" @default.
- W2497567508 modified "2023-09-24" @default.
- W2497567508 title "Virtual bound state contribution to the crystal field potential" @default.
- W2497567508 doi "https://doi.org/10.1016/b978-008043608-1/50014-9" @default.
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