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- W2497741525 abstract "The study reported herein describes multifunctional effect of layered double hydroxide (LDH) modified with phosphonium-based ionic liquids (IL) containing phosphinate, carboxylate and phosphate anions on progress of ring-opening polymerization of ε-caprolactone under microwave irradiation. The extent of IL-modification had a crucial effect on the exfoliation of LDH. The non-modified LDH was able to catalyse the ring-opening polymerization of ε-caprolactone with polymer yield 89% but provided only micro-composite material. On the contrary, LDH with intercalated IL-anions promoted exfoliation of LDH after only 3 min of microwave irradiation. The developed process is fast, environmentally-friendly (solvent-free) and adaptable to various polymer matrices, since a broad variety of IL-anions might be applied." @default.
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- W2497741525 date "2016-09-01" @default.
- W2497741525 modified "2023-10-16" @default.
- W2497741525 title "Influence of ionic liquid-modified LDH on microwave-assisted polymerization of ε-caprolactone" @default.
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- W2497741525 doi "https://doi.org/10.1016/j.polymer.2016.08.014" @default.
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