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• W2497788169 abstract "Yolk-shell (Y-S) structured Fe3O4@void@CdS nanoparticles (NPs) are synthesized through a one-pot coating-etching process with Fe3O4@SiO2 as the core, where the coating of an outer CdS shell from a chemical bath deposition (CBD) process is simultaneously accompanied by the gradual etching of an inner SiO2 shell. The as-prepared Fe3O4@void@CdS NPs (ca. 200 nm) possess good monodispersity and a uniform CdS shell of ca.15 nm. This composite exhibits excellent photo-Fenton (ph-F) activity toward the degradation of methylene blue (MB) in a wide pH working range of 4.5-11 under the visible light irradiation. A series of control experiments demonstrate the unique Y-S structure contributes to the enhanced activity, where the separation of hole-electron pair from CdS and the reduction of Fe(2+) from Fe(3+) are mutually promoted. The similar efficiency can also be achieved when the shell component changes to TiO2 or CeO2, demonstrating a general strategy for the design of robust ph-F agent." @default.
• W2497788169 created "2016-08-23" @default.
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• W2497788169 date "2016-08-08" @default.
• W2497788169 modified "2023-10-10" @default.
• W2497788169 title "Synthesis of Yolk–Shell Structured Fe₃O₄@void@CdS Nanoparticles: A General and Effective Structure Design for Photo-Fenton Reaction" @default.
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• W2497788169 doi "https://doi.org/10.1021/acsami.6b07644" @default.
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