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• W2498107130 abstract "The stereochemical outcome of [1,3]-sigmatropic rearrangements can be rationalized by the use of olefinic tau (τ) bonds, and by considering that diradical intermediates have pyramidal character." @default.
• W2498107130 created "2016-08-23" @default.
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• W2498107130 date "2016-01-01" @default.
• W2498107130 modified "2023-10-16" @default.
• W2498107130 title "Bent bonds and the antiperiplanar hypothesis – a simple model to rationalize [1,3]-sigmatropic alkyl shifts" @default.
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• W2498107130 doi "https://doi.org/10.1039/c6ob01139j" @default.
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