Matches in SemOpenAlex for { <https://semopenalex.org/work/W2498492745> ?p ?o ?g. }
Showing items 1 to 70 of
70
with 100 items per page.
- W2498492745 endingPage "340" @default.
- W2498492745 startingPage "327" @default.
- W2498492745 abstract "The observed magnetic properties of the unligated Fe(II) porphyrins were reproduced by theoretical calculations taking into account all possible configuration interactions and spin—orbit coupling interactions. The calculated results were in good agreement with the observations only when it was assumed that the axial ligand field is so weak that the dz2 orbital is close to the dπ and dxy orbitals. The low-lying states are 3A2, 3E, 5E, 5B2 and 5A1. The ground state has two sublevels with eigenvectors that are quantum mechanical admixtures of triplet states (3A2, 3E) and quintet states (5A1). The Mössbauer quadrupole splitting should be attributed to the less temperature-dependent bonding-orbital contribution, however, the d-orbital contribution is almost constant for the ground sublevels and thus a change in the Boltzmann distribution between the sublevels yields no appreciable change in the quadrupole splitting." @default.
- W2498492745 created "2016-08-23" @default.
- W2498492745 creator A5006641222 @default.
- W2498492745 creator A5036845016 @default.
- W2498492745 creator A5061854517 @default.
- W2498492745 date "1980-12-10" @default.
- W2498492745 modified "2023-09-25" @default.
- W2498492745 title "Intermediate-Spin States of Iron Porphyrins" @default.
- W2498492745 doi "https://doi.org/10.1021/ba-1980-0191.ch018" @default.
- W2498492745 hasPublicationYear "1980" @default.
- W2498492745 type Work @default.
- W2498492745 sameAs 2498492745 @default.
- W2498492745 citedByCount "0" @default.
- W2498492745 crossrefType "book-chapter" @default.
- W2498492745 hasAuthorship W2498492745A5006641222 @default.
- W2498492745 hasAuthorship W2498492745A5036845016 @default.
- W2498492745 hasAuthorship W2498492745A5061854517 @default.
- W2498492745 hasConcept C121332964 @default.
- W2498492745 hasConcept C131538251 @default.
- W2498492745 hasConcept C147120987 @default.
- W2498492745 hasConcept C184779094 @default.
- W2498492745 hasConcept C185592680 @default.
- W2498492745 hasConcept C189394030 @default.
- W2498492745 hasConcept C26873012 @default.
- W2498492745 hasConcept C2779451542 @default.
- W2498492745 hasConcept C27799899 @default.
- W2498492745 hasConcept C39984356 @default.
- W2498492745 hasConcept C41999313 @default.
- W2498492745 hasConcept C42704618 @default.
- W2498492745 hasConcept C4839761 @default.
- W2498492745 hasConcept C57805442 @default.
- W2498492745 hasConcept C62520636 @default.
- W2498492745 hasConcept C69523127 @default.
- W2498492745 hasConcept C97355855 @default.
- W2498492745 hasConceptScore W2498492745C121332964 @default.
- W2498492745 hasConceptScore W2498492745C131538251 @default.
- W2498492745 hasConceptScore W2498492745C147120987 @default.
- W2498492745 hasConceptScore W2498492745C184779094 @default.
- W2498492745 hasConceptScore W2498492745C185592680 @default.
- W2498492745 hasConceptScore W2498492745C189394030 @default.
- W2498492745 hasConceptScore W2498492745C26873012 @default.
- W2498492745 hasConceptScore W2498492745C2779451542 @default.
- W2498492745 hasConceptScore W2498492745C27799899 @default.
- W2498492745 hasConceptScore W2498492745C39984356 @default.
- W2498492745 hasConceptScore W2498492745C41999313 @default.
- W2498492745 hasConceptScore W2498492745C42704618 @default.
- W2498492745 hasConceptScore W2498492745C4839761 @default.
- W2498492745 hasConceptScore W2498492745C57805442 @default.
- W2498492745 hasConceptScore W2498492745C62520636 @default.
- W2498492745 hasConceptScore W2498492745C69523127 @default.
- W2498492745 hasConceptScore W2498492745C97355855 @default.
- W2498492745 hasLocation W24984927451 @default.
- W2498492745 hasOpenAccess W2498492745 @default.
- W2498492745 hasPrimaryLocation W24984927451 @default.
- W2498492745 hasRelatedWork W1992537723 @default.
- W2498492745 hasRelatedWork W1998204182 @default.
- W2498492745 hasRelatedWork W2033046343 @default.
- W2498492745 hasRelatedWork W2046339872 @default.
- W2498492745 hasRelatedWork W2052117044 @default.
- W2498492745 hasRelatedWork W2078093079 @default.
- W2498492745 hasRelatedWork W2078267595 @default.
- W2498492745 hasRelatedWork W2103139334 @default.
- W2498492745 hasRelatedWork W2262489272 @default.
- W2498492745 hasRelatedWork W2607356973 @default.
- W2498492745 isParatext "false" @default.
- W2498492745 isRetracted "false" @default.
- W2498492745 magId "2498492745" @default.
- W2498492745 workType "book-chapter" @default.