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- W2498611456 abstract "A variety of fluorine-containing polymers of vinyl ethers with well-defined structures were synthesized by base-assisting living cationic polymerization. Well-controlled reactions were achieved in various fluorinated solvents, which had not been examined as solvents for cationic polymerization. Excellent living nature of the reactions allowed precision synthesis of block and star-shaped polymers with controlled sequences. The resulting fluorinated polymers with appropriate fluorine content underwent highly sensitive upper critical solution temperature (UCST)-type phase separation in organic solvents with a range of polarities including perfluoro versions. The unique solubility permitted thermoresponsive physical gelation with solutions of star block or heteroarm star polymers." @default.
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- W2498611456 date "2012-01-01" @default.
- W2498611456 modified "2023-09-27" @default.
- W2498611456 title "Well-Defined Fluorine-Containing Star Polymers of Vinyl Ethers: Precision Synthesis by Base-Assisting Living Cationic Polymerization and Thermoresponsive Solubility Transitions" @default.
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- W2498611456 doi "https://doi.org/10.1021/bk-2012-1106.ch005" @default.
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