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- W2499634472 abstract "With the Pb doping content at Sr-site increasing, a series of Sr1-xPbxLi2Ti6O14 (x = 0, 0.25, 0.50, 0.75, 1.0) are synthesized by a simple solid-state reaction. It is found that the reversible capacity and rate capability experience a parabolic course from SrLi2Ti6O14 to PbLi2Ti6O14. Among all the as-prepared samples, Sr0.5Pb0.5Li2Ti6O14 shows the best cycling and rate properties. It delivers an initial charge capacity of 163.2 mAh g−1 at 100 mA g−1 with the capacity retention of 96.08% after 100 cycles. In addition, it can also deliver a reversible capacity of 141.8 mAh g−1 at 700 mA g−1. The superior electrochemical properties of Sr0.5Pb0.5Li2Ti6O14 are attributed to the reduced charge transfer resistance and increased lithium-ion diffusion coefficient after doping. Besides, in-situ X-ray diffraction is also performed to investigate the lithium-ion insertion/extraction behaviors of SrLi2Ti6O14, Sr0.5Pb0.5Li2Ti6O14 and PbLi2Ti6O14. The observed results confirm that Sr0.5Pb0.5Li2Ti6O14 has good structural stability and reversibility for repeated lithium storage." @default.
- W2499634472 created "2016-08-23" @default.
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- W2499634472 date "2016-09-01" @default.
- W2499634472 modified "2023-10-15" @default.
- W2499634472 title "Complex titanates Sr1-xPbxLi2Ti6O14 (0≤x≤1) as anode materials for high-performance lithium-ion batteries" @default.
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- W2499634472 doi "https://doi.org/10.1016/j.electacta.2016.07.090" @default.
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