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- W2499668739 abstract "Free radical polymerization in a latex particle occurs at polymer concentrations where chain entanglements and low free volume can significantly reduce the translational and segmental mobility of macroradicals. The termination reaction becomes diffusion-controlled and a reduction in the termination rate constant by several orders of magnitude can cause a large increase in the average number of radicals per particle and an acceleration in the rate of polymerization. At higher conversions a glassy-state transition may occur with the propagation reaction rate falling rapidly and approaching rates which are typical of solid state polymerizations. In the normal time scale a limiting conversion of less than 100% is reached. When molecular weight development is controlled mainly by termination reactions, a dramatic increase in the weight average molecular weight is observed at high conversions. In emulsion polymerizations chain transfer reactions are generally more important and thus molecular weight increases with conversion are not large." @default.
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- W2499668739 date "1981-10-07" @default.
- W2499668739 modified "2023-10-16" @default.
- W2499668739 title "Emulsion Polymerization Kinetics" @default.
- W2499668739 doi "https://doi.org/10.1021/bk-1981-0165.ch019" @default.
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