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- W2500105230 abstract "Cationic ring-opening polymerization of epichlorohydrin, using triethyloxonium hexafluorophosphate initiator in the presence of ethylene glycol to produce a low molecular weight polyepichlorohydrin glycol, was examined. A new polymerization mechanism was postulated that: polymerization initiates at the hydroxyl groups in the ethylene glycol, and the polymer chain propagates simultaneously at both ends through the addition of the monomer. In this polymerization system, the polymer molecular weight increases directly with the polymer conversion, and it can be controlled by the molar ratio of epichlorohydrin and ethylene glycol. The obtained polyepichlorohydrin glycols possess predominantly secondary hydroxyl groups, narrow molecular weight distribution, and a hydroxyl functionality of 2. Byproducts formed in polyepichlorohydrin glycol are identified as non-functional cyclic oligomers, mainly epichlorohydrin cyclopentamer and cyclohexamer." @default.
- W2500105230 created "2016-08-23" @default.
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- W2500105230 date "1985-08-16" @default.
- W2500105230 modified "2023-09-24" @default.
- W2500105230 title "Cationic Ring-Opening Polymerization of Epichlorohydrin in the Presence of Ethylene Glycol" @default.
- W2500105230 doi "https://doi.org/10.1021/bk-1985-0286.ch025" @default.
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