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- W2500175066 abstract "The polymerization of maleic anhydride, norbornene and various norbornene derivatives, including the Diels-Alder adducts of cyclopentadiene with maleic anhydride, N-phenylmaleimide, acrylonitrile and methyl acrylate, is initiated by the addition of a peroxide or peroxyester having a short half life and undergoing rapid decomposition at the reaction temperature. The higher the temperature the higher the conversion with catalysts having the same halflife, i.e. less than 60 min, at temperature. The polymerizations of MAH, norbornene and the CPD-MAH and CPD-NPMI Diels-Alder adducts are subject to a dilution effect and are suppressed when the solvent concentration is greater than 25%. The polymerizability of these monomers, unreactive under normal conditions, in the presence of peroxides undergoing rapid decomposition, the condition wherein chemically induced dynamic nuclear polarization is observed, is consistent with their tendency to undergo photosensitized reactions under ultraviolet light." @default.
- W2500175066 created "2016-08-23" @default.
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- W2500175066 date "1983-04-19" @default.
- W2500175066 modified "2023-09-24" @default.
- W2500175066 title "Temperature and Dilution Effects in Polymerization Induced by Peroxides Undergoing Rapid Decomposition (t1/2 <60 Minutes)" @default.
- W2500175066 doi "https://doi.org/10.1021/bk-1983-0212.ch031" @default.
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