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- W2500346980 abstract "Pressure sensitive paints (PSP) have proved to be revolutionary in the design of aircraft, cars, trucks, and other vehicles. In this study we incorporate highly hosphorescent divalent osmium complexes into PSP. The divalent osmium complexes were of the form [Os(N-N)2 L-L] (PF6-) 2 where N-N was a derivative of 1,10-phenanthroline, and L-L was either cis-1,2-bis(diphenylphosphino)ethene, cis-1,2-vinylenebis-(diphenylarsine), or bis(diphenylarseno) methane. The complexes were dissolved into poly(2-[ethyl- heptadecafluorooctyl)-sulfonyl]amino]ethylmethacrylate) at a concentration of 1 mg complex to 1000 mg of polymer. The paints were tested for pressure sensitivity, temperature dependence, and photo-degradation. The paints featured strong pressure response, and luminescence intensity change by up to a factor of two. The temperature dependence was measured as low as -0.1% °C-1. Many of the complexes exhibited almost non-existent photo-degradation." @default.
- W2500346980 created "2016-08-23" @default.
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- W2500346980 date "2007-03-13" @default.
- W2500346980 modified "2023-09-27" @default.
- W2500346980 title "Pressure Sensing Paints Based on Fluoroacrylic Polymers Doped with Phosphorescent Divalent Osmium Complexes" @default.
- W2500346980 doi "https://doi.org/10.1021/bk-2007-0957.ch008" @default.
- W2500346980 hasPublicationYear "2007" @default.
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