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- W2500447992 abstract "Grafting reactions to cellulose and its derivatives began in the early 1950's. There has been intense research and development activity in the field since those early days and many hundreds of papers and patents have been published. In spite of all this effort there has been comparatively little commercialization of the grafting process. The turning around of this situation represents the greatest challenge to those of us who are active in the field. The reasons for the lack of industrialization on a large scale have been partly economic and partly the ability of researchers to find alternative means to achieve comparable properties. The author feels, however, that the situation will change once certain technical challenges are met. A number of these are discussed together with some still promising fields of application. Among the technical problems which still remain to a considerable extent are the concurrent formation of homopolymer in most cases, and the lack of reproducibility in these largely heterogeneous reactions. In addition, the grafted side chains are often too few and too long, leading to a limited involvement also of the cellulose molecules themselves. Although there is often some concurrent degradation of the cellulose itself, this is not believed to be normally an important consideration." @default.
- W2500447992 created "2016-08-23" @default.
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- W2500447992 date "1982-06-18" @default.
- W2500447992 modified "2023-09-27" @default.
- W2500447992 title "Some Challenges in Grafting to Cellulose and Cellulose Derivatives" @default.
- W2500447992 doi "https://doi.org/10.1021/bk-1982-0187.ch001" @default.
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