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- W2500614882 abstract "The design and synthesis of a ferroelectric bow-phase (banana-phase) composed of racemic molecules is described. To date many hundreds of bent-core molecules have been screened for liquid crystallinity, motivated by the recent discovery of very unusual and interesting chiral, antiferroelectric smectic phases from achiral molecules. Based upon a model for bow-phase antiferroelectric structure driven by layer interface clinicity, incorporation of one racemic methylheptyloxycarbonyl tail into the prototype bow-shaped mesogen structure was accomplished. This led to a material showing the unmistakable B7 texture by polarized light microscopy. This B7 phase was shown to be ferroelectric by a combination of electrooptic properties and current response in 4μm transparent capacitor liquid crystal cells. To our knowledge, this is the first ferroelectric smectic LC composed of racemic molecules." @default.
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- W2500614882 date "2001-11-02" @default.
- W2500614882 modified "2023-09-25" @default.
- W2500614882 title "Design of Smectic Liquid Crystal Phases Using Layer Interface Clinicity" @default.
- W2500614882 doi "https://doi.org/10.1021/bk-2001-0798.ch020" @default.
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