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- W2500697968 abstract "The advantages of using crystalline solids (particularly single crystals) for optical absorption and linear dichroism measurements are well known (1). Less widely appreciated perhaps are the advantages (and limitations) of extending this technique to the measurement of optical activity. Although many of the points below apply equally well to magnetically induced optical activity, the primary emphasis of our work has been on the measurement of natural optical activity as a technique for studying conformation and absolute configuration. These data can serve as important bench marks since independent (X-ray) determination of absolute configuration and conformation is frequently possible (2). The relatively low dipole strengths of d-d and certain other low lying, highly forbidden electronic transitions makes solid state optical activity measurements particularly applicable to transition metal ion complexes. For intrinsically chiral species that are inert enough to be resolved conventionally, the measurement of natural optical activity in crystals has the same" @default.
- W2500697968 created "2016-08-23" @default.
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- W2500697968 date "1980-05-27" @default.
- W2500697968 modified "2023-09-26" @default.
- W2500697968 title "Photoacoustic Detection of Natural Circular Dichroism in Crystalline Transition Metal Complexes" @default.
- W2500697968 doi "https://doi.org/10.1021/bk-1980-0119.ch020" @default.
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