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- W2500826306 abstract "ESR studies of pristine poly-[1,6-bis(N-carbazolyl)-2,4-hexadiyne] (poly-DCH), a member of the general class of materials known as polydiacetylene, of the reaction of poly-DCH with bromine, and of poly-DCHBr6 are reported and compared to previously reported ESR studies on similar systems. The ESR studies include measurements of the spectral linewidths, the g-tensors and the relative ESR signal intensity as a function of temperature for poly-DCH and poly-DCHBr6. Briefly, for pristine poly-DCH, two superimposed ESR spectra are observed. The spectral linewidths and g-tensors are independent of temperature. In contrast, the ESR signal intensity is thermally activated and displays two activation energies. The kinetics of the disappearance of the original ESR spectrum observed in pristine poly-DCH and its replacement with a different ESR spectral envelope is presented as are the kinetic parameters which describe the reaction of poly-DCH with bromine." @default.
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- W2500826306 date "1987-03-26" @default.
- W2500826306 modified "2023-09-25" @default.
- W2500826306 title "Electron Paramagnetism in Poly(1,6-di-N-carbazolyl-2,4-hexadiyne) and Its Bromine Derivatives" @default.
- W2500826306 doi "https://doi.org/10.1021/bk-1987-0337.ch019" @default.
- W2500826306 hasPublicationYear "1987" @default.
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