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- W2501718860 abstract "Models which have been considered in the various analytical treatments of statistical thermodynamic and configurational behaviour of adsorbed polymer layers most often ignore such important characteristics of the adsorbate molecules as the excluded-volume effect and bond rotational hindrance (1,2,3,4,5). Further, the procedures used for introducing solvent and concentration effects are less satisfactory (6). The present analytical developments are thus limited to oversimplified models that would have only a little correspondence with real systems. It is, therefore, desirable to investigate alternative approaches which would be effective in the study of more realistic models. The success of Monte Carlo computer simulation method in investigating the configurational and thermodynamic behaviour of systems involving polymer molecules assuming models of varying complexity is well established (7,8,9). This approach is based on the assumption that it is possible to generate a random sample of molecular configurations which would adequately simulate the canonical ensemble corresponding to the" @default.
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- W2501718860 date "1975-06-01" @default.
- W2501718860 modified "2023-09-26" @default.
- W2501718860 title "Configurational Behavior of Isolated Chain Molecules Adsorbed from Athermal Solutions" @default.
- W2501718860 doi "https://doi.org/10.1021/bk-1975-0008.ch002" @default.
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