Matches in SemOpenAlex for { <https://semopenalex.org/work/W2501768658> ?p ?o ?g. }
Showing items 1 to 86 of
86
with 100 items per page.
- W2501768658 endingPage "44" @default.
- W2501768658 startingPage "36" @default.
- W2501768658 abstract "Abstract High pressure phase equilibria measurements of long chain saturated methyl esters (methyl decanoate, methyl dodecanoate, methyl tetradecanoate, methyl hexadecanoate, methyl octadecanoate and methyl docosanoate) in supercritical ethane have been measured for temperatures between 312 K and 355 K and for methyl ester mass fractions from 0.65 to 0.018. The results show a generally linear relationship between the phase equilibria pressure and the temperature with complete mutual solubility above 17 MPa. No three-phase regions or temperature inversions (change in sign of gradient of temperature–pressure relationship at constant composition) were observed while maxima in the phase transition pressures were found for methyl ester mass fractions usually between 0.2 and 0.3. When the phase transition pressure is plotted as a function of carbon number at constant temperature and mass fraction methyl ester, a linear relationship is realised. This linear relationship can be used to determine the solubility of any saturated methyl ester with between 10 and 22 carbon atoms, with limited extrapolation being possible. Thermodynamic modelling of the measured phase equilibria with the sPC-SAFT and Peng Robinson equations of state showed that, even with the use of an interaction parameter, these equations of state are not able to model the phase behaviour and the linear pressure–carbon numbers provide more accurate predictions." @default.
- W2501768658 created "2016-08-23" @default.
- W2501768658 creator A5026160944 @default.
- W2501768658 creator A5047245955 @default.
- W2501768658 creator A5057692676 @default.
- W2501768658 creator A5061549731 @default.
- W2501768658 date "2011-12-01" @default.
- W2501768658 modified "2023-09-26" @default.
- W2501768658 title "Phase behaviour of high molecular mass methyl esters in supercritical ethane" @default.
- W2501768658 cites W1964100655 @default.
- W2501768658 cites W1979275139 @default.
- W2501768658 cites W1979902696 @default.
- W2501768658 cites W2005592384 @default.
- W2501768658 cites W2008312376 @default.
- W2501768658 cites W2008559758 @default.
- W2501768658 cites W2011662462 @default.
- W2501768658 cites W2013023405 @default.
- W2501768658 cites W2016613469 @default.
- W2501768658 cites W2017905754 @default.
- W2501768658 cites W2021808069 @default.
- W2501768658 cites W2028303240 @default.
- W2501768658 cites W2029051831 @default.
- W2501768658 cites W2030905907 @default.
- W2501768658 cites W2034481158 @default.
- W2501768658 cites W2041099420 @default.
- W2501768658 cites W2048845068 @default.
- W2501768658 cites W2063215927 @default.
- W2501768658 cites W2064485520 @default.
- W2501768658 cites W2070197805 @default.
- W2501768658 cites W2070795529 @default.
- W2501768658 cites W2077568922 @default.
- W2501768658 cites W2083226986 @default.
- W2501768658 cites W2085237940 @default.
- W2501768658 cites W2129288307 @default.
- W2501768658 cites W2158922243 @default.
- W2501768658 cites W24237376 @default.
- W2501768658 cites W4244905632 @default.
- W2501768658 cites W171992559 @default.
- W2501768658 doi "https://doi.org/10.1016/j.fluid.2011.08.015" @default.
- W2501768658 hasPublicationYear "2011" @default.
- W2501768658 type Work @default.
- W2501768658 sameAs 2501768658 @default.
- W2501768658 citedByCount "9" @default.
- W2501768658 countsByYear W25017686582012 @default.
- W2501768658 countsByYear W25017686582013 @default.
- W2501768658 countsByYear W25017686582014 @default.
- W2501768658 countsByYear W25017686582015 @default.
- W2501768658 countsByYear W25017686582016 @default.
- W2501768658 countsByYear W25017686582018 @default.
- W2501768658 countsByYear W25017686582019 @default.
- W2501768658 countsByYear W25017686582023 @default.
- W2501768658 crossrefType "journal-article" @default.
- W2501768658 hasAuthorship W2501768658A5026160944 @default.
- W2501768658 hasAuthorship W2501768658A5047245955 @default.
- W2501768658 hasAuthorship W2501768658A5057692676 @default.
- W2501768658 hasAuthorship W2501768658A5061549731 @default.
- W2501768658 hasConcept C118419359 @default.
- W2501768658 hasConcept C178790620 @default.
- W2501768658 hasConcept C185592680 @default.
- W2501768658 hasConcept C43617362 @default.
- W2501768658 hasConcept C44280652 @default.
- W2501768658 hasConceptScore W2501768658C118419359 @default.
- W2501768658 hasConceptScore W2501768658C178790620 @default.
- W2501768658 hasConceptScore W2501768658C185592680 @default.
- W2501768658 hasConceptScore W2501768658C43617362 @default.
- W2501768658 hasConceptScore W2501768658C44280652 @default.
- W2501768658 hasLocation W25017686581 @default.
- W2501768658 hasOpenAccess W2501768658 @default.
- W2501768658 hasPrimaryLocation W25017686581 @default.
- W2501768658 hasRelatedWork W1988192344 @default.
- W2501768658 hasRelatedWork W2046854371 @default.
- W2501768658 hasRelatedWork W2086626270 @default.
- W2501768658 hasRelatedWork W2088669026 @default.
- W2501768658 hasRelatedWork W2317452413 @default.
- W2501768658 hasRelatedWork W2336842786 @default.
- W2501768658 hasRelatedWork W2604890884 @default.
- W2501768658 hasRelatedWork W2949229842 @default.
- W2501768658 hasRelatedWork W2995758399 @default.
- W2501768658 hasRelatedWork W4231634193 @default.
- W2501768658 hasVolume "311" @default.
- W2501768658 isParatext "false" @default.
- W2501768658 isRetracted "false" @default.
- W2501768658 magId "2501768658" @default.
- W2501768658 workType "article" @default.