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- W2501886717 endingPage "388" @default.
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- W2501886717 abstract "A series of new rhodium (I) complexes supported by bidentate nitrogen-donor ligands with varying electronic and steric properties were synthesized in situ and evaluated for catalytic arene C–H/D activation. In trifluoroacetic acid (HTFA), these complexes are proposed to mediate H/D exchange of arene C–H/D bonds by an electrophilic aromatic substitution mechanism that involves Rh-mediated activation of HTFA (or DTFA). DFT calculations support the proposed pathway for the H/D exchange reactions." @default.
- W2501886717 created "2016-08-23" @default.
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- W2501886717 date "2017-01-01" @default.
- W2501886717 modified "2023-09-28" @default.
- W2501886717 title "Electrophilic RhI catalysts for arene H/D exchange in acidic media: Evidence for an electrophilic aromatic substitution mechanism" @default.
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- W2501886717 doi "https://doi.org/10.1016/j.molcata.2016.07.045" @default.
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