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- W2502196181 abstract "Effect of /spl gamma/-ray irradiation on the charge behavior of polyethersulfone (PES) is investigated through the measurement of thermally stimulated current (TSC). Each sample is irradiated by /spl gamma/-rays in air at room temperature to various total doses less than 30 kGy. In the TSC spectra obtained after a poling process at 37/spl deg/C, /spl beta/ peak at 150/spl deg/C increases first with an increase in the dose up to 0.61 kGy, and then decreases. The /spl gamma/ peak which is not observed in the non-irradiated sample appears at 100/spl deg/C in the irradiated sample. Similarly to the /spl beta/ peak, the /spl gamma/ peak increases in the low dose region and decreases if the irradiation dose exceeds 1 kGy. When the sample is poled at 120/spl deg/C, the /spl gamma/ peak is not observed and the /spl beta/ peak decreases monotonically as the dose increases. It is considered that scission of polymer main chains occurs during the /spl gamma/-ray irradiation and that rearrangement of main chains from a loose packing to a more rigid packing occurs while the sample is heated during the TSC measurement. This molecular rearrangement is considered to be the origin of the /spl gamma/ peak and also related to the decrease of the charge quantity of TSC." @default.
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- W2502196181 date "2002-11-22" @default.
- W2502196181 modified "2023-09-23" @default.
- W2502196181 title "Effect of γ-ray irradiation on the thermally stimulated current in polyethersulfone" @default.
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- W2502196181 doi "https://doi.org/10.1109/icpadm.1997.616557" @default.
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