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- W2502255655 abstract "Introduction: Macromolecules that can form transient associations via their end-groups or pendant groups have found increasing interest because of their unique rheological properties. They are receiving attention as replacement for high molecular weight viscosifiers in applications such as paints, coating, oil recovery, or controlled drug release. Such systems can flow under shear like a viscous fluid, but recover rapidly gel-like behaviors at low shear rate or at rest. Owing to the formation of reversible connections between the polymer chains, these physical gels also exhibit self-heal capacity, and sensitivity to stimuli that can modify the strength of the connections (pH, salt, and temperature...). In water-based media, hydrophobe-bearing polymers (HP) have been recognized for their striking thickening efficiency due to the self-association of pendant hydrophobes groups (1-2, 3). One difficulty, however, in handling such polymers is the slow dissolution rate, and possible gel blocking of the concentrated stock solutions. These drawbacks are" @default.
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- W2502255655 date "2002-10-15" @default.
- W2502255655 modified "2023-09-25" @default.
- W2502255655 title "Photoresponsive Thickening in Polyamphiphile-Based Physical Gels: The Examples of Micelle, Protein, and Cyclodextrin Cross-Linkers" @default.
- W2502255655 doi "https://doi.org/10.1021/bk-2002-0833.ch018" @default.
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