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- W2502863875 abstract "Smectites contribute much of the inorganic surface area of soils and therefore have a large potential for influencing the fate of atrazine in soil environments. The sorption capacity of smectites for atrazine varies widely depending on the surface charge density of the smectite, nature of the adsorbed cation, and pH of the equilibrating solution. Under neutral conditions, molecular atrazine is initially sorbed on smectites by a combination of water bridging between electronegative moieties on the atrazine molecule and adsorbed metal cations and hydrophobic bonding between the alkyl-side chains on the atrazine molecule and hydrophobic microsites on the smectite surface. Surface acidity, arising principally from enhanced hydrolysis of solvation water for adsorbed metal cations, catalyzes protonation and hydrolysis of atrazine sorbed on smectite surfaces. The hydrolysis product is protonated hydroxy/keto-atrazine, which may exist in any of 14 different tautomeric forms. Tautomerism and resonance allow protonated hydroxy/keto-atrazine to adapt to heterogeneous microsites on smectite surfaces which results in strong bonding." @default.
- W2502863875 created "2016-08-23" @default.
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- W2502863875 date "1996-06-21" @default.
- W2502863875 modified "2023-09-27" @default.
- W2502863875 title "Interactions Between Atrazine and Smectite Surfaces" @default.
- W2502863875 doi "https://doi.org/10.1021/bk-1996-0630.ch008" @default.
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