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- W2503144073 abstract "The ammoximation of ketones with H 2 O 2 and NH 3 was conducted over various titanosilicates, and the effects of reaction parameters and the ammoximation mechanism were investigated. The catalytic performance of Ti-MWW greatly depended on the method of addition of the reactant. Superior to TS-1, Ti-Beta and Ti-MOR, Ti-MWW showed the conversion and oxime selectivity both as high as 99% for many ketones in the presence of water. The ammoximation proceeded in two separate steps: primarily the catalytic oxidation of NH 3 by H 2 O 2 to NH 2 OH and secondarily the non-catalytic oximation of ketones with NH 2 OH to oximes." @default.
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- W2503144073 date "2007-01-01" @default.
- W2503144073 modified "2023-10-16" @default.
- W2503144073 title "Liquid-phase Ammoximation over Ti-MWW: High Efficiency, Reaction Conditions and Mechanism" @default.
- W2503144073 doi "https://doi.org/10.1016/b978-0-444-53202-2.50079-8" @default.
- W2503144073 hasPublicationYear "2007" @default.
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