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- W2503224512 abstract "Abstract Poly(acrylic acid)s ( PAAs ) with curable methacrylamide moieties as well as bisacrylamide crosslinkers are described as components for well‐defined hydrogels with increased hydrolytic resistance. PAAs with tethered curing moieties of different alkyl spacer lengths (−( CH 2 ) n −, n = 2, 3, 6 or 8) were prepared via copolymerization of one‐sided methacrylated diamines with protected acrylic acid, followed by polymer‐analogous methacrylation and deprotection. Bisacrylamide crosslinkers were synthesized by acrylation of diamines with different cores and N‐substitutes like allyl, cyclopropyl or propyl groups. Both components were subsequently combined for the formation of novel amide based hydrogels. Network densities of the obtained gels were elucidated by rheokinetic investigations. © 2016 Society of Chemical Industry" @default.
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- W2503224512 date "2016-07-15" @default.
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- W2503224512 title "Tailored hydrolytically stable polyacid gels based on curable poly(acrylic acid)s and bisacrylamides" @default.
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- W2503224512 doi "https://doi.org/10.1002/pi.5179" @default.
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