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- W2503367427 abstract "Results of small-angle-neutron-scattering (SANS), static and dynamic light scattering, NMR and rheological measurements on solutions of Alkylpyridiniumsalicylates (RPySal) and Alkyltrimethylammoniumsalicylates (RTASal) are presented and discussed. The data indicate the existence of rodlike micelles whose lengths L increase linearly with increasing concentration, until a critical concentration c* is reached at which L approaches to the mean distance D between the rods. Above c* the L-values decrease with increasing concentration. Addition of an electrolyte (NaCl) shifts c* towards lower values. Below c* the unsheared solutions are not elastic and have low viscosities; the viscosity and the elasticity rise drastically when c* is surpassed. In order to explain this elasticity, the formation of a threedimensional network above c* must be assumed. The dynamic nature of this network can be seen from the storage modulus G′ which increases with increasing angular frequency ω and reaches a rubber plateau at a characteristic ω-value." @default.
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- W2503367427 date "1985-03-27" @default.
- W2503367427 modified "2023-10-13" @default.
- W2503367427 title "Viscoelastic Detergent Solutions from Rodlike Micelles" @default.
- W2503367427 doi "https://doi.org/10.1021/bk-1985-0272.ch004" @default.
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