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- W2503676318 abstract "The increasing importance of photopolymeric materials for lithography and the manufacture of microcircuits has led to an increased understanding of the photochemical processes in solid polymers. Although polymers are known to react readily in solution, the fact that they may be equally reactive in the solid phase has not been generally appreciated. In this paper we will discuss the characteristics of photochemical reactions of the ketone chromophore, both in solid and liquid systems. Since it is generally accepted that chemical reactions of small molecules in solution and in the gas phase occur as a result of activated collisions, it was expected that reactions would not occur in solid matrices because of the restrictions on molecular motion imposed by the solid. However, as we will see, organic polymeric materials, even in the glassy state, retain substantial freedom of motion of individual groups down to very low temperatures and these are often" @default.
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- W2503676318 date "1985-07-01" @default.
- W2503676318 modified "2023-10-16" @default.
- W2503676318 title "Photochemistry of Ketone Polymers in the Solid Phase: A Review" @default.
- W2503676318 doi "https://doi.org/10.1021/bk-1984-0266.ch006" @default.
- W2503676318 hasPublicationYear "1985" @default.
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