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- W2504714975 abstract "This chapter proposes a method of quantitative estimation of electron-donor ability of ligands that is based upon principally new geometric model of crystal structures. Within this model, the atoms are considered as deformable spheres of the fixed volume and the whole structure as a closest three-dimensional packing of these atoms. This packing is equivalent to the Voronoi-Dirichlet partition. The model is in agreement with the existing experimental data and classical concepts of the complex formation in uranyl-based systems. In addition, the model provides a unique framework for the interpretation of the experimental facts. The power of the proposed model and its predictive ability is most likely due to the fact that the 3-dimensional image of chemical bonds in crystals has many advantages over the classic 1-dimensional description." @default.
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- W2504714975 date "2007-01-01" @default.
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- W2504714975 title "Some features of stereochemistry of U(VI)" @default.
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- W2504714975 doi "https://doi.org/10.1016/b978-044452111-8/50003-x" @default.
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