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• W2505087287 abstract "Dipolar cycloaddition of polycyclic azomethine ylides, in which the central nitrogen atom is part of a pyrrolidine ring and bears a methoxycarbonyl group with norbornenes has been shown to produce two main types of products featuring pyrrolizidine rings. In conjuction with results of quantum chemical calculations (B3LYP), mechanistic rationale was postulated. The key reaction step is unprecedented endocyclic to exocyclic azomethine ylide rearrangement by an intermolecular prototropic migration (formal [1,3] H‐shift)." @default.
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• W2505087287 date "2014-09-24" @default.
• W2505087287 modified "2023-10-05" @default.
• W2505087287 title "Dipolar Cycloaddition Reactions of Azomethine Ylides Generated by endocyclic-exocyclic 1,3-dipole Rearrangement" @default.
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• W2505087287 doi "https://doi.org/10.1002/jhet.2167" @default.
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